Effects of nitrogen fertilization on aromatic compounds of muskmelon

doi:10.6048/j.issn.1001-4330.2023.12.015

Xinjiang Agricultural Sciences ›› 2023, Vol. 60 ›› Issue (12): 2993-3007.DOI: 10.6048/j.issn.1001-4330.2023.12.015

• Horticultural Special Local Products·Plant Protection • Previous Articles Next Articles

Effects of nitrogen fertilization on aromatic compounds of muskmelon

ZHANG Hao¹^,²(), LIU Yi³, ZHOU Bo¹^,², HUANG Yuan³, FU Xiaofa¹^,², MA Yue⁴, WU Haibo²^,⁵, HU Guozhi⁵, MAO Jiancai⁵, CHEN Jihao¹^,²(), LIANG Qigan¹^,², WANG Min⁶()

1. Hainan Sanya Crops Breeding Trial Center of Xinjiang Academy Agricultural Sciences, Sanya Hainan 572000, China
2. Sanya Mingzhu Melon and Watermelon Variety Demonstration Evaluation and Research Center, Sanya Hainan 572000, China
3. Huazhong Agricultural University, Wuhan 430070, China
4. Fruit Research Institute of Chinese Academy Agricultural Sciences in Zhengzhou, Zhengzhou 450000, China
5. The Research Center of Hami Melon,Xinjiang Academy of Agricultural Sciences, Urumqi 830091, China
6. Vegetable Research Institute of Hainan Academy Agricultural Sciences,Haikou 570100, China

Received:2023-04-21 Online:2023-12-20 Published:2024-01-03
Correspondence author: CHEN Jihao (1987-), male, master, assistant researcher, engaged in research on crop genetics and breeding, (E-mail)389708326@qq.com;WANG Min(1970-),male,Researcher,Research focuses on the physiology of melon cultivation,(E-mail)13005022331@163.com
Supported by:
Specific Research Fund of the Innovation Platform for Academicians of Hainan Province(YSPTZX202141);Innovation Platform for Academicians of Hainan Province;Hainan Natural Science Foundation(321QN382);Natural Science Foundation of Xinjiang Uygur Autonomous Region(2021D01B59);Independent Cultivation Special Project of Xinjiang Academy of Agricultural Sciences(xjnkyzzp-2022006)

氮素运筹对甜瓜芳香物质的影响

张浩¹^,²(), 刘熠³, 周勃¹^,², 黄远³, 符小发¹^,², 马跃⁴, 吴海波²^,⁵, 胡国智⁵, 毛建才⁵, 陈积豪¹^,²(), 梁其干¹^,², 王敏⁶()

1.新疆农业科学院海南三亚农作物育种试验中心,海南三亚 572000
2.三亚明珠甜瓜西瓜展示评价研究中心,海南三亚 572000
3.华中农业大学,武汉 430070
4.中国农业科学院郑州果树研究所,郑州 450000
5.新疆农业科学院哈密瓜研究中心,乌鲁木齐 830091
6.海南省农业科学院蔬菜研究所,海口 570100

通讯作者: 陈积豪(1987-),男,海南乐东人,助理研究员,研究方向为甜瓜栽培与生理,(E-mail)389708326@qq.com;王敏(1970-),男,海南乐东人,研究员,研究方向为甜瓜栽培生理学,(E-mail)13005022331@163.com
作者简介:张浩(1987-),男,甘肃定西人,助理研究员,硕士,研究方向为甜瓜栽培与生理,(E-mail)842760455@qq.com
基金资助:
海南省院士创新平台科研专项(YSPTZX202141);海南省院士创新平台;海南省自然科学基金青年基金项目(321QN382);新疆维吾尔自治区自然科学基金项目(2021D01B59);新疆农业科学院自主培育专项(xjnkyzzp-2022006)

Abstract

Abstract:

【Objective】To study the effects of nitrogen application on the flavor quality of melon at maturity stage in the hope of enhancing technical measures to improve its flavor quality.【Methods】The melon variety Huang Mengcui melon fruits were taken as the test material to study of nitrogen transport effects under different nitrogen fertilizations: N₀ (Nitrogen deficiency), N₁(Low nitrogen), N₂(Medium nitrogen), N₃(High nitrogen),CK(no fertilization)and M(Organic fertilizer)on the aromatic compounds and nutritional quality of the fruit in Sanya.【Results】In terms of the types of aromatic substances, a total of 346 aromatic substances were detected in the six treatments, of which 25 were commonly found, mainly alcohols, aldehydes, and esters. The total and unique types of aromatic substances under low nitrogen treatment are the highest, with 167 and 12 species, respectively. Aromatic substances that appear with increasing nitrogen levels include ethyl butyrate, ethyl propionate, ethyl 2-methylbutyrate, 2-Butyn-1-one, 1-cyclohexyl-4,4-diethoxy -, (E) - non 6-en 1-ol, etc; the highest ester content in high nitrogen treatment was 12.28%, while the lowest ester content in nitrogen deficiency treatment was 4.81%. The characteristic aromatic substance ethyl acetate showed an increasing trend with the increase of nitrogen application rate, while the increase of methyl acetate nitrogen application rate showed a trend of first increasing and then decreasing; the highest soluble solid content in the high nitrogen treatment center was 15.40%, while the lowest soluble solid content in the M treatment center was 13.40%. The maximum weight of a single melon under medium nitrogen treatment is 1.95 kg, and the minimum CK is 1.74 kg.【Conclusion】Under the condition of different nitrogen levels, the composition and content of aromatic substances in melon changed, resulting in the difference in the content of common aromatic substances and the existence of unique characteristic components. N₁ treatment was beneficial to increase the type and relative content of aromatic substances; N₂ and N₃ treatments increased single fruit weight and content of soluble solids, respectively.

Key words: nitrogen; muskmelon; aromatic compound; quality

摘要：

【目的】研究氮素运筹对甜瓜果实芳香物质变化的影响,为提高甜瓜风味品质的技术措施提供依据。【方法】以甜瓜品种黄梦脆为试材,在设施栽培条件下研究氮素运筹6个处理(N₀:缺氮;N₁:低氮;N₂:中氮;N₃:高氮;CK:不施肥;M:有机肥)对甜瓜芳香物质变化规律。【结果】6个处理共检出346种芳香物质,其中共有的芳香物质为 25种,主要为醇类、醛类和酯类。低氮处理芳香物质总种类及特有种类最多,分别有167和12种。随着氮素水平增加而出现的芳香物质有:丁酸乙酯、丙酸乙酯、2-甲基丁酸乙酯、2-Butyn-1-one, 1-cyclohexyl-4,4-diethoxy-、(E)-non-6-en-1-ol等;高氮处理酯类含量最高为12.28%,缺氮处理酯类最低为4.81%。特征芳香物质乙酸乙酯随着施氮量的增加有增加趋势,乙酸甲酯施氮量的增加有先升后降的趋势;高氮处理中心可溶性固形物含量最高为15.40%,M处理中心可溶性固形物含量最低为13.40%。中氮处理单瓜重最高为1.95 kg,CK最低为1.74 kg。【结论】不同氮素水平条件下会引起甜瓜芳香物质的成分、含量的变化,导致共有芳香物质种类含量的差异以及特有特征成分的存在;低氮处理有利于丰富甜瓜芳香物质的种类和提高甜瓜特征芳香物质乙酸丁酯、乙酸己酯的相对含量;中氮、高氮处理分别提高单果重和中心可溶性固形物含量。

关键词: 氮素, 甜瓜, 芳香, 品质

CLC Number:

S562
S14

ZHANG Hao, LIU Yi, ZHOU Bo, HUANG Yuan, FU Xiaofa, MA Yue, WU Haibo, HU Guozhi, MAO Jiancai, CHEN Jihao, LIANG Qigan, WANG Min. Effects of nitrogen fertilization on aromatic compounds of muskmelon[J]. Xinjiang Agricultural Sciences, 2023, 60(12): 2993-3007.

张浩, 刘熠, 周勃, 黄远, 符小发, 马跃, 吴海波, 胡国智, 毛建才, 陈积豪, 梁其干, 王敏. 氮素运筹对甜瓜芳香物质的影响[J]. 新疆农业科学, 2023, 60(12): 2993-3007.

Figures/Tables 4

References 29

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处理 Treatment	纯养分量Pure nutrients(kg/667m²)
处理 Treatment	N	P₂O₅	K₂O
1(不施氮)	0	244	160
2	160	244	160
3	200	244	160
4	240	244	160
CK	0	0	0
M	0	0	0

处理 Treatment	纯养分量Pure nutrients(kg/667m²)
处理 Treatment	N	P₂O₅	K₂O
1(不施氮)	0	244	160
2	160	244	160
3	200	244	160
4	240	244	160
CK	0	0	0
M	0	0	0

处理 Deal with	相对含量 Relative content(%)
处理 Deal with	醇类 Alcohols	醛类 Aldehydes	酸类 Acids	酯类 Esters	酮醚类 Ketone ethers	环类 Ring class	烃类 Hydrocarbons	其他类别 Other categories
CK	34.79±1.43^b	43.01±3.36^a	0.54±0.17^b	12.01±2.73^a	4.92±0.83^a	2.39±1.20^a	1.12±0.81^a	0.55±0.30^a
M	40.11±2.39^ab	46.10±2.14^a	0.87±0.16^ab	4.86±0.69^b	4.29±0.42^a	2.12±0.68^a	0.72±0.44^a	0.94±0.27^a
N₀	47.11±4.12^a	38.08±3.04^a	1.28±0.15^a	4.81±0.61^b	4.56±0.58^a	1.79±0.84^a	1.86±0.47^a	0.51±0.17^a
N₁	38.21±1.86^b	43.06±5.13^a	0.87±0.34^ab	9.22±3.29^ab	2.47±1.08^a	2.73±1.37^a	1.54±1.36^a	0.53±0.26^a
N₂	35.76±1.52^b	45.10±0.93^a	0.57±0.04^b	9.58±2.25^ab	4.89±0.23^a	2.17±0.77^a	1.44±0.69^a	0.48±0.10^a
N₃	33.05±3.27^b	47.96±3.21^a	0.29±0.02^b	12.28±1.39^a	3.52±0.91^a	1.74±0.79^a	0.89±0.59^a	0.27±0.19^a

处理 Deal with	相对含量 Relative content(%)
处理 Deal with	醇类 Alcohols	醛类 Aldehydes	酸类 Acids	酯类 Esters	酮醚类 Ketone ethers	环类 Ring class	烃类 Hydrocarbons	其他类别 Other categories
CK	34.79±1.43^b	43.01±3.36^a	0.54±0.17^b	12.01±2.73^a	4.92±0.83^a	2.39±1.20^a	1.12±0.81^a	0.55±0.30^a
M	40.11±2.39^ab	46.10±2.14^a	0.87±0.16^ab	4.86±0.69^b	4.29±0.42^a	2.12±0.68^a	0.72±0.44^a	0.94±0.27^a
N₀	47.11±4.12^a	38.08±3.04^a	1.28±0.15^a	4.81±0.61^b	4.56±0.58^a	1.79±0.84^a	1.86±0.47^a	0.51±0.17^a
N₁	38.21±1.86^b	43.06±5.13^a	0.87±0.34^ab	9.22±3.29^ab	2.47±1.08^a	2.73±1.37^a	1.54±1.36^a	0.53±0.26^a
N₂	35.76±1.52^b	45.10±0.93^a	0.57±0.04^b	9.58±2.25^ab	4.89±0.23^a	2.17±0.77^a	1.44±0.69^a	0.48±0.10^a
N₃	33.05±3.27^b	47.96±3.21^a	0.29±0.02^b	12.28±1.39^a	3.52±0.91^a	1.74±0.79^a	0.89±0.59^a	0.27±0.19^a

处理 Deal with	单瓜重 Single melon weight (kg)	中心可溶性固形物 Heartsoluble solids (%)	果皮厚 Thickness (cm)	果肉含水率 Water content of pulp (%)
CK	1.74±0.13^a	14.67±0.28^a	0.70±0.06^b	92.68±0.77^a
N₀	1.88±0.10^a	15.27±0.53^a	0.73±0.09^b	91.70±0.50^a
N₁	1.90±0.09^a	14.63±0.12^a	0.70±0.10^b	92.13±0.46^a
N₂	1.95±0.17^a	15.07±0.15^a	1.03±0.07^a	92.88±0.66^a
N₃	1.86±0.07^a	15.40±0.12^a	0.83±0.07^ab	92.97±0.33^a
M	1.89±0.06^a	13.40±0.15^b	0.93±0.03^ab	92.94±0.36^a

Effects of nitrogen fertilization on aromatic compounds of muskmelon

氮素运筹对甜瓜芳香物质的影响

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序号 Serial number	英文名称 English name		中文名称 Chinese name		分子式 Molecular formula			相对含量 Relative content (%)
序号 Serial number	英文名称 English name		中文名称 Chinese name		分子式 Molecular formula			CK		M		N₀		N₁		N₂		N₃
	Alcohol		醇类
1	4-[(1-Ethylpropyl)amino]-2-methyl-3, 5-dinitrobenzenemethanol		4-[(1-乙基丙基)氨基] -2-甲基-3,5-二硝基苯甲醇		C₁₃H₁₉N₃O₅			0.004		0.001		-		-		-		-
2	2-(OCTADECYLOXY)ETHANOL		2-(十八氧基)乙醇		C₂₀H₄₂O₂			-		-		-		0.014		-		0.015
3	HEPTAETHYLENE GLYCOL MONODODECYL ETHER		十二烷基七聚乙二醇醚		C₂₆H₅₄O₈			0.022		-		-		-		-		-
4	Octaethylene glycol monododecyl ether		辛乙烯二醇单正十二烷基酯		C₂₈H₅₈O₉			-		-		-		0.013		-		0.019
5	3-Buten-2-one, 4-(4-hydroxy-2,2,6-trimethyl-7-oxabicyclo[4.1.0]hept-1-yl)-		/		C₁₃H₂₀O₃			-		-		-		0.028		-		0.045
6	4-Hydroxy-2-butanone		4-羟基-2-丁酮		C₄H₈O₂			0.077		0.185		0.235		0.083		0.097		0.020
7	Cyclopentanol, 1-(1-methylene-2-propenyl)-		/		C₉H₁₄O			0.028		-		0.081		-		-		-
8	phenylethyl alcohol		苯乙醇		C₈H₁0O			0.135		0.048		0.153		0.017		0.110		0.021
9	(E)-hept-3-en-1-ol		/		C₇H₁₄O			-		-		-		0.042		-		-
10	(3R,4S,5Z)-5-Hexen-3-ol, 6-chloro-2,4-dimethyl-,		/		C₈H₁₅ClO			-		-		-		-		-		0.038
11	benzyl alcohol		苯甲醇		C₇H₈O			0.728		0.344		0.469		0.297		0.424		0.285
12	2H-Pyran-2-methanol, tetrahydro-		四氢吡喃-2-甲醇		C₆H₁₂O₂			0.052		-		-		-		0.037		-
13	4H-3,1-Benzoxazine, 4a,5,6,7,8, 8a-hexahydro-4,8-dimethyl-2-phenyl-, (4α,4aα,8β,8aβ)- (9CI)		/		C₁₆H₂₁NO			-		-		-		0.025		-		-
14	E-non-3-en-1-ol		/		C₉H₁₈O			-		-		-		-		-		0.038
15	(Z)-3-decenol		顺-3-癸醇		C₁₀H₂₀O			-		0.056		0.041		0.065		0.045		-
16	(Z)-3-nonen-1-ol		顺-3-壬烯-1-醇		C₉H₁₈O			-		-		2.110		-		-		-
17	Bicyclo[2.2.1]heptane-2,5-diol, 1,7,7-trimethyl-, (1R,2S,4R,5R)-rel-		/		C₁₀H₁₈O₂			-		-		0.118		-		-		-
18	α-terpineol		alpha-松油醇		C₁₀H₁₈O			-		-		-		-		-		0.284
19	1-Heptatriacotanol		/		C₃₇H₇₆O			0.004		-		0.004		0.009		-		-
20	1-hexanol		正己醇		C₆H₁₄O			-		-		-		-		-		0.312
21	1-heptanol		正庚醇		C₇H₁₆O			0.032		0.054		0.049		0.105		0.082		0.066
22	1-octanol		正辛醇		C₈H₁₈O			4.487		5.164		4.874		3.778		4.869		4.565
23	3-Buten-2-one, 4-(4-hydroxy-2,6, 6-trimethyl-1-cyclohexen-1-yl)-, (3E)-		/		C₁₃H₂₀O₂			-		-		-		0.003		-		-
24	3-Methyl-1-butanol		异戊醇		C₅H₁₂O			-		0.059		-		-		-		-
25	NOPOL		6,6-二甲基-二环[3.1.1]庚-2-烯-2-乙醇		C₁₁H₁₈O			-		0.004		-		-		0.018		-
26	4-Cyclooctene-1-methanol		/		C₉H₁₆O			-		-		0.051		-		-		-
27	2-methyl-1-butanol		2-甲基丁醇		C₅H₁₂O			0.081		0.081		0.101		0.105		0.102		0.082
28	Z,Z-2,5-Pentadecadien-1-ol		/		C₁₅H₂₈O			-		0.008		-		0.010		-		-
29	1-nonanol	1-壬醇		C₉H₂₀O				-		-		2.790		-		1.348		1.366
30	Cyclodecanol	环癸醇		C₁₀H₂₀O				-		-		-		0.035		-		-
31	9-Oxabicyclo[3.3.1]nonane-2,6-diol	/		C₈H₁₄O₃				-		0.004		-		-		-		-
32	Fenchol	小茴香醇		C₁₀H₁₈O				0.092		0.067		0.072		-		0.077		0.046
33	TRANS-2-DECEN-1-OL	2-癸烯-1-醇		C₁₀H₂₀O				0.049		-		-		-		-		0.044
34	BETA-IONOL	beta-紫罗兰醇		C₁₃H₂₂O				-		-		0.004		-		-		-
35	2-nonen-1-ol	2-壬烯-1-醇		C₉H₁₈O				0.146		0.042		0.052		0.335		0.141		0.086
36	L-Menthol	薄荷醇		C₁₀H₂₀O				0.016		0.008		0.016		-		0.012		-
37	2-Methylene-5α-cholestan-3β-ol	/		C₂₈H₄₈O				0.028		-		-		-		0.024		0.004
38	2-methyl - 1-Hexadecanol	2-甲基-1-十六烷醇		C₁₇H₃₆O				0.007		-		-		-		-		-
39	trans,cis-2,6-Nonadien-1-ol	反-2,顺6-壬二烯醇		C₉H₁₆O				0.348		0.381		0.334		0.866		0.277		0.148
40	2-Pentadecyn-1-ol	/		C₁₅H₂₈O				-		-		-		0.173		0.191		0.132
41	(E)-2-nonenol	反式-2-壬烯-1-醇		C₉H₁₈O				-		0.109		0.078		0.280		0.104		-
42	(E)-non-6-en-1-ol	/		C₉H₁₈O				-		-		-		3.782		-		1.843
43	1-octen-3-ol	1-辛烯-3-醇		C₈H₁₆O				1.067		1.060		0.985		0.258		0.517		0.202
44	(6Z)-Nonen-1-ol	(Z)-6-壬烯-1-醇		C₉H₁₈O				2.838		3.955		3.126		4.716		2.822		2.167
45	E-7-Tetradecenol	/		C₁₄H₂₈O				-		0.009		-		0.043		0.012		0.017
46	1-Methylcycloheptanol	1-甲基环庚醇		C₈H₁₆O				0.122		0.053		0.067		-		0.119		0.064
47	cis-p-Mentha-2,8-dien-1-ol	1-哌嗪羧酸,3-(羟基甲基)- 4-(苯基甲基)-1,1-二甲基乙基酯		C₁₀H₁₆O				0.008		0.006		0.008		0.026		-		0.004
48	3,7-Dimethyl-2-octen-1-ol	3,7-二甲基-6-辛烯-1-醇		C₁₀H₂₀O				0.022		-		-		-		-		-
49	(-)-Drimenol	(-)-补身醇		C₁₅H₂₆O				-		-		0.057		-		-		-
50	Desulphosinigrin	/		C₁₀H₁₇NO₆S				-		-		0.008		0.003		0.016		-
51	Thujyl alcohol	蒽紫红素		C₁₀H₁₈O				0.016		-		0.020		-		0.012		0.012
52	3-hexen-1-ol	2-甲硫基乙醇		C₃H₈OS				-		-		0.687		-		-		-
53	Cyclopentanepropanol, 2-methylene-	/		C₉H₁₆O				-		0.045		-		0.508		0.068		-
54	3,5-DIMETHYLCYCLOHEXANOL	3,5-二甲基环己醇		C₈H₁₆O				-		-		-		0.045		-		-
55	terpinen-4-ol	4-萜烯醇		C₁₀H₁₈O				0.048		0.043		0.074		0.031		0.035		0.037
56	13-Heptadecyn-1-ol	13-十七炔-1-醇		C₁₇H₃₂O				0.004		-		-		-		-		-
57	3,6-(E,Z)-nonadien-1-ol	3,6-亚壬基-1-醇		C₉H₁₆O				0.981		1.530		1.850		1.559		1.643		1.424
58	BETA-D-LACTOSE	β-乳糖		C₁₂H₂₂O₁₁				0.012		0.013		-		0.013		0.014		-
59	3-Pentanol, 2,4-dimethyl-	2,4-二甲基-3-戊醇		C₇H₁₆O				-		-		-		-		-		0.032
60	CIS-4-HEPTEN-1-OL		顺-4-庚烯-1-醇			C₇H₁₄O		0.062		0.087		0.055		0.043		0.053		0.062
61	5-Methyl-1-hexyn-3-ol		5-甲基-1-己炔-3-醇			C₇H₁₂O		-		-		-		-		-		0.004
62	3-Buten-1-ol, 2-methyl-4-(2,6,6-trimethyl-1-cyclohexen-1-yl)-, (E)- (9CI)		/			C₁₄H₂₄O		0.012		-		-		-		0.008		-
63	9-Oxabicyclo[3.3.1]non-6-en-2-one, oxime		/			C₈H₁₁NO₂		0.036		-		-		-		-		-
64	3,7,11-TRIMETHYL-1-DODECANOL		3,7,11-三甲基十二烷醇			C₁₅H₃₂O		0.022		-		0.008		0.003		0.014		0.008
65	(+)-trans,trans-5-Caranol		/			C₁₀H₁₈O		-		-		0.060		-		-		-
66	2,4-DIMETHYLCYCLOHEXANOL		2,4-二甲基环己醇			C₈H₁₆O		-		-		-		-		-		0.050
67	Panaxydol		人参环氧炔醇			C₁₇H₂₄O₂		-		0.018		-		-		-		-
68	CIS-2-METHYLCYCLOHEXANOL		cis-2-甲基环己醇			C₇H₁₄O		-		-		-		0.021		-		-
69	5,7-Dodecadiyn-1,12-diol		5,7-十二烷二炔-1,12-二醇			C₁₂H₁₈O₂		-		0.004		-		0.045		0.037		-
70	3,5-Heptadien-2-ol, 2,6-dimethyl-		/			C₉H₁₆O		-		-		-		0.003		-		-
71	Cedrol		柏木脑			C₁₅H₂₆O		0.004		-		-		-		-		-
72	2,4-Undecadien-1-ol		/			C₁₁H₂₀O		-		-		-		0.052		-		-
73	TRANS,CIS-2,6-NONADIEN-1-OL		反-2,顺6-壬二烯醇			C₉H₁₆O		-		-		0.066		0.867		0.130		-
74	alpha-Terpineol		α-松油醇			C₁₀H₁₈O		0.322		0.301		0.520		0.171		0.206		0.277
	Aldehyde		醛类
75	Cyclohexanebutanal, 2-methyl-3-oxo-, cis- (9CI)		/			C₁₁H₁₈O₂		-		-		-		-		-		0.030
76	(E,E)-2,4-heptadienal		(E,E)-2,4-庚二烯醛			C₇H₁₀O		0.099		0.033		0.050		-		0.040		0.024
77	benzaldehyde		苯甲醛			C₇H₆O		0.004		0.004		0.004		-		0.005		0.004
78	decanal		癸醛			C₁₀H₂₀O		0.052		0.062		-		0.076		0.088		0.040
79	benzeneacetaldehyde		苯乙醛			C₈H₈O		0.040		-		-		-		0.039		-
80	octanal		正辛醛			C₈H₁₆O		1.484		0.984		2.109		0.508		1.914		1.857
81	nonanal		壬醛			C₉H₁₈O		1.177		2.405		1.031		2.773		1.590		1.656
82	(E)-2-nonenal		反式-2-壬醛			C₉H₁₆O		2.210		2.509		1.923		2.246		2.636		2.859
83	2-Dodecenal, (E)-		反-2-十二烯醛			C₁₂H₂₂O		-		-		-		-		-		0.004
84	2-Methyl-4-(2,6,6-trimethyl-1-cyclohexenyl)butanal		/			C₁₄H₂₄O		0.029		0.054		0.025		0.068		-		-
85	(Z,Z)-3,6-nonadienal		顺-3,顺-6-壬二烯醛			C₉H₁₄O		-		0.100		0.023		-		0.118		0.103
86	(Z)-4-nonenal		(Z)-4-壬烯醛			C₉H₁₆O		0.125		0.157		0.074		0.062		0.084		0.203
87	(Z)-6-nonenal		(Z)-6-壬烯醛			C₉H₁₆O		2.830		4.595		2.694		4.199		2.997		3.534
88	6-nonenal		(E)-6-壬烯醛			C₉H₁₆O		-		-		3.769		3.467		3.399		2.896
89	2-Undecenal		2-十一烯醛			C₁₁H₂₀O		0.454		-		-		-		-		-
90	(E)-2-Octenal		(Z)-2-辛烯醛			C₈H₁₄O		0.149		0.240		0.086		-		0.142		-
91	9,12,15-Octadecatrienal		/			C₁₈H₃₀O		-		-		-	-		-		0.004
92	Boronal		Α,2,6,6-四甲基-1-环己烯-1-巴豆醛			C₁₄H₂₂O		-		-		0.004	-		0.008		-
93	2,4-Dimethyl-2,4-heptadienal		/			C₉H₁₄O		-		-		-	0.049		-		-
94	β-cyclocitral		BETA-环柠檬醛			C₁₀H₁₆O		0.711		-		0.757	-		-		-
95	2,6,6-trimethyl-1-cyclohexene-1-acetaldehyde		2,6,6-三甲基-1-环己烯基乙醛			C₁₁H₁₈O		0.055		0.038		0.045	0.043		0.049		0.037
96	(E, Z)-2,6-nonadienal		反-2-,顺-6-壬二烯醛			C₉H₁₄O		3.760		2.486		2.869	3.347		3.633		4.446
97	10-Octadecenal		10-十八醛			C₁₈H₃₄O		-		-		-	0.003		-		-
98	4-Octadecenal		/			C₁₈H₃₄O		-		-		-	-		-		0.004
99	2-Bromooctadecanal		2-溴十八碳A萘基			C₁₈H₃₅BrO		0.049		0.015		0.014	-		0.027		0.025
100	Bicyclo[6.1.0]nonane, 9-(1-methylethylidene)-		/			C₁₂H₂₀		-		-		-	-		-		0.053
101	(Z)-7-Hexadecenal		(Z)-7-十六碳烯醛			C₁₆H₃₀O		0.012		0.004		-	0.013		-		0.004
102	(Z)-2-Heptenal		2-庚烯醛			C₇H₁₂O		-		0.009		-	-		-		0.575
103	(E,E)-2,4-Nonadienal		(E,E)-2,4-壬二烯醛			C₉H₁₄O		0.034		0.058		0.033	-		0.063		0.068
104	(Z)-non-2-enal		(Z)-2-壬烯醛			C₉H₁₆O		-		-		-	0.056		-		-
105	hexanal		正己醛			C₆H₁₂O		0.969		0.981		0.718	0.562		0.811		0.749
106	(E)-2-hexenal		顺-2-已烯醛			C₆H₁₀O		1.188		0.823		0.895	0.738		0.869		1.005
107	(Z)-4-heptenal		CIS-4-庚烯醛			C₇H₁₂O		0.004		0.004		0.005	0.004		0.006		0.006
108	Undecan-4-olide		桃醛			C₁₁H₂₀O₂		0.030		-		-	-		-		0.028
	Acid		酸类
109	3-HYDROXYDODECANOIC ACID		3-羟基月桂酸			C₁₂H₂₄O₃		0.030		0.069		0.080	0.069		-		0.087
110	2-HydroxyMyristic Acid		2-羟基十四烷酸			C₁₄H₂₈O₃		-		-		-	-		0.032		-
111	nonanoic acid		壬酸			C₉H₁₈O₂		0.071		-		-	-		0.122		-
112	Oleic Acid		油酸			C₁₈H₃₄O₂		0.071		-		0.008	-		0.126		0.066
113	2,2-DIMETHYLVALERIC ACID		2,2-二甲基戊酸			C₇H₁₄O₂		0.004		-		-	-		-		-
114	2-ethylhexanoic acid		异辛酸			C₈H₁₆O₂		0.032		-		-	-		-		-
115	(Z,Z,Z)-8,11,14-Eicosatrienoic acid		顺式-8,11,14-二十烷三烯酸甲酯			C₂₀H₃₄O₂		0.020		0.013		0.016	0.048		0.040		0.008
116	9-Hexadecenoic acid		顺式-9-十六烯酸			C₁₆H₃₀O₂		0.012		0.015		0.008	0.008		-		-
117	Hexadecenoic acid, Z-11-		/			C₁₆H₃₀O₂		-		-		-	-		0.009		-
118	cis-10-Heptadecenoic acid		顺式-10-十七烯酸			C₁₇H₃₂O₂		0.079		-		-	-		-		-
119	Tricyclo[4.3.1.1(3,8)]undecane-1-carboxylic acid		三环[4.3.1.1(3,8)]十一烷-1-羧酸			C₁₂H₁₈O₂		-		-		-	0.003		-		0.004
120	17-Octadecynoic acid		17-十八炔酸			C₁₈H₃₂O₂		-		-		0.025	-		0.014		-
121	cis-Vaccenic acid		顺式十八碳烯酸			C₁₈H₃₄O₂		0.011		-		-	-		-		-
122	trimethylthioacetic S-acid		硫代特戊酸			C₅H₁₀OS	-		0.173		0.115		0.319		0.095		-
123	oxaluric acid		3-脲基乙酸			C₃H₄N₂O₄		-		-		0.293		0.093		-		-
124	Pentanoic acid, 4-methyl-		4-甲基戊酸			C₆H₁₂O₂	0.040		-		-		-		-		-
125	trans-13-Octadecenoic acid		反式-13-十八碳烯酸			C₁₈H₃₄O₂	-		-		-		-		-		0.041
126	4-Amino-1,5-pentandioic acid		4-氨基庚二酸			C₇H₁₃NO₄		-		0.099		-		-		-		-
127	1-Allylcyclopropanecarboxylic acid		1-烯丙基环丙基甲酸			C₇H₁₀O₂		-		0.062		-		-		-		-
128	Pterin-6-carboxylic acid		蝶呤-6-羧酸			C₇H₅N₅O₃		0.004		-		-		-		-		-
	Ester		酯类
129	(+/-)-3-HYDROXY-GAMMA-BUTYROLACTONE		(+/-)-β-羟基-γ-丁内酯			C₄H₆O₃		-		0.127		0.175		-		-		-
130	Acetamide, N-methyl-N-[4-[2-acetoxymethyl-1-pyrrolidyl]-2-butynyl]-		/			C₁₄H₂₂N₂O₃		0.052		0.013		-		0.009		0.045		-
131	Spironolactone		螺内酯			C₂₄H₃₂O₄S		-		-		0.043		0.013		0.014		-
132	γ-Dodecalactone		γ-十二内酯			C₁₂H₂₂O₂		-		-		-		0.017		-		-
133	Methyl 2,6,10,14-tetramethylpentadecanoate		/			C₂₀H₄₀O₂		0.004		-		0.004		-		-		-
134	methyl 12-(2-octylcyclopropyl)dodecanoate		/			C₂₄H₄₆O₂		0.004		0.004		0.004		0.009		0.010		0.004
135	gamma-Nonanolactone		丙位壬内酯			C₉H₁₆O₂		0.030		-		-		-		-		0.034
136	ethyl propanoate		丙酸乙酯			C₅H₁₀O₂		0.284		-		-		0.278		0.114		0.262
137	ethyl butanoate		丁酸乙酯			C₆H₁₂O₂		-		-		-		0.052		-		0.606
138	9-Oxabicyclo[3.3.1]nonan-2-ol, acetate		/			C₁₀H₁₆O₃		0.068		-		-		-		0.020		-
139	Isopropyl acetate		乙酸异丙酯			C₅H₁₀O₂		-		0.222		-		0.004		-		-
140	Carbonic acid, butyl hexahydro-4a,8, 8-trimethyl-3H-3,8a-ethano-1,2-benzodioxin-7-yl ester		/			C₁₈H₃₀O₅		0.008		0.004		0.004		0.004		0.004		0.004
141	Geranyl isovalerate		(E)-3,7-二甲基-2,6-辛二烯醇 3-甲基丁酸酯			C₁₅H₂₆O₂		0.011		-		-		0.007		-		-
142	3-methylbutyl formate		甲酸异戊酯			C₆H₁₂O₂		0.047		-		-		-		-		-
143	2,3-butanediyl diacetate		/		C₈H₁₄O₄			0.027		-		0.075		-		0.179		0.099
144	octyl acetate		乙酸辛酯		C₁₀H₂₀O₂			-		-		0.045		-		-		0.075
145	HEPTYL FORMATE		/		C₈H₁₆O₂			-		-		-		-		-		0.071
146	Isobornyl thiocyanoacetate		/			C₁₃H₁₉NO₂S		-		-		-		0.017		-		0.008
147	3-methyl-2-buten-1-yl acetate		梨醇酯			C₇H₁₂O₂		-		-		-		-		-		0.008
148	ethyl hexanoate		正己酸乙酯			C₈H₁₆O₂		-		-		-		-		-		0.016
149	butyl acetate		乙酸丁酯			C₆H₁₂O₂		0.004		-		-		0.021		0.016		0.014
150	1-Butanol, 3-methyl-, acetate		乙酸异戊酯			C₇H₁₄O₂		-		-		-		0.128		-		0.028
151	trans-Pulegone oxide		/			C₁₀H₁₆O₂		0.285		-		-		0.212		-		-
152	3-Mercaptohexyl butanoate		3-巯基己醇丁酸酯			C₁₀H₂₀O₂S		0.036		-		-		-		0.049		0.044
153	1-Oxaspiro[4.5]decan-3-carboxylic acid, 2-oxo-4-cyano-, ethyl ester		/			C₁₃H₁₇NO₄		-		-		-		-		-		0.004
154	ethyl acetate		乙酸乙酯			C₄H₈O₂		2.489		0.763		1.061		1.497		1.947		2.455
155	Pregnan-20-one, 3-(acetyloxy)-5,6:16,17-diepoxy-, (3β,5α,6α,16α)-		/			C₂₃H₃₂O₅		-		0.025		-		0.030		-		-
156	hexyl acetate		乙酸己酯			C₈H₁₆O₂		-		0.064		-		0.121		0.114		0.087
157	2-Octenoic acid, 2-hexenyl ester, (E,E)- (9CI)		/			C₁₄H₂₄O₂		-		-		-		-		0.004		-
158	DIHYDROACTINIDIOLIDE		二氢猕猴桃内酯			C₁₁H₁₆O₂		-		-		-		0.010		-		-
159	(E)-10-Heptadecen-8-ynoic acid methyl ester		/			C₁₈H₃₀O₂		0.012		0.021		0.020		0.012		0.023		0.018
160	3-methylbenzyl acetate		3-甲基苯甲基乙酸酯			C₁₀H₁₂O₂		-		0.041		-		0.048		-		-
161	2,3-dihydroxypropyl (9Z,12Z,15Z)-9,12,15-octadecatrienoate		甘油亚麻酸酯			C₂₁H₃₆O₄		-		-		-		-		0.073		-
162	2-Trifluoroacetoxydodecane		/			C₁₄H₂₅F₃O₂		-		-		0.004		-		-		-
163	2,4,5,6,7,7a-Hexahydro-3,6-dimethyl- α-methylene-2-oxo-6-vinyl-5-benzofuranacetic acid methyl ester		/			C₁₆H₂₀O₄		-		-		-		0.004		-		-
164	9-Octadecenoic acid (Z)-, hexyl ester		油酸正己酯			C₂₄H₄₆O₂		-		0.008		-		-		-		-
165	2,6-Diethylphenyl isocyanate		2,6-二乙基异氰酸苯酯			C₁₁H₁₃NO		-		-		-		0.014		-		-
166	(Z,Z,Z)-8,11,14-Eicosatrienoic acid, methyl ester		顺式-8,11,14-二十烷三烯酸甲酯			C₂₁H₃₆O₂		0.008		-		-		0.015		-		0.004
167	Methyl 2-methylhexanoate		2-甲基-己酸甲酯			C₈H₁₆O₂		-		-		-		-		-		0.004
168	(E)-9-Tetradecen-1-olacetate		(E)-9-十四碳烯-1-醇乙酸酯			C₁₆H₃₀O₂		0.060		0.018		0.030		-		-		-
169	Pentanoic acid, 2,2,4-trimethyl-3-hydroxy-, isobutyl ester		/			C₁₂H₂₄O₃		0.040		-		-		-		-		-
170	(22E,24R)-24-Methylcholesta-5,22-dien-3β-ol acetate		/			C₃₀H₄₈O₂		-		-		0.008		0.003		-		0.004
171	2-ETHYLHEXYL BUTYRATE		丁酸(2-乙基己基)酯			C₁₂H₂₄O₂		0.007		-		-		-		-		-
172	METHYL ARACHIDONATE		花生四烯酸甲酯			C₂₁H₃₄O₂		0.012		0.004		0.006		0.095		0.004		0.004
173	Methoprene		烯虫酯			C₁₉H₃₄O₃		-		-		-		-		0.012		-
174	Bufalin		蟾毒灵			C₂₄H₃₄O₄		-		0.008		-		-		0.012		0.004
175	Pentyl phenylacetate		苯乙酸戊酯			C₁₃H₁₈O₂		0.008		-		-		0.004		-		-
176	Cyclopropanetetradecanoic acid, 2-octyl-, methyl ester		/			C₂₆H₅₀O₂		0.007		0.063		-		0.008		0.059		0.008
177	2-Butanol, 3-methyl-, acetate		1,2-二甲基丙醇乙酸酯			C₇H₁₄O₂		-		0.024		0.012		-		0.009		-
178	TRANS-2-UNDECENAL		反-2-十一烯醛			C₁₁H₂₀O		0.493		-		-		0.368		-		-
179	9-Octadecenoic acid (Z)-, phenylmethyl ester		油酸苄酯			C₂₅H₄₀O₂		0.008		0.008		0.006		-		0.004		-
180	3,6-Octadecadiynoic acid, methyl ester		3,6-十八碳二炔酸甲酯			C₁₉H₃₀O₂		-		-		-		0.004		0.008		-
181	2,5-Octadecadiynoic acid, methyl ester		2,5-十八碳二炔酸甲酯			C₁₉H₃₀O₂		0.040		0.064		0.033		0.013		0.026		0.023
182	12,15-Octadecadiynoic acid, methyl ester		/			C₁₉H₃₀O₂		0.005		0.004		0.004	0.003		0.014		0.004
183	2-Heptanol, acetate		1-甲基己醇乙酸酯			C₉H₁₈O₂		-		-		-	0.389		-		-
184	2-methyl-1-butanol acetate		2-甲基丁基乙酸酯			C₇H₁₄O₂		0.020		0.025		0.012	0.028		0.033		-
185	1-METHYLBUTYL ACETATE		乙酸仲戊酯			C₇H₁₄O₂		0.004		-		-	-		0.008		-
186	Amyl acetate		乙酸戊酯			C₇H₁₄O₂		0.021		0.013		-	-		-		0.008
187	Diethyleneglycol diacetate		二乙二醇二乙酸酯			C₈H₁₄O₅		-		-		-	0.010		-		-
188	Pentanoic acid, 2-propenyl ester		戊酸烯丙酯			C₈H₁₄O₂		-		-		-	-		-		0.036
189	2,2,4-Trimethyl-1,3-pentanediol diisobutyrate		2,2,4-三甲基-1,3-戊二醇二异丁酸酯			C₁₆H₃₀O₄		-		-		-	0.007		-		-
190	Formic acid, ethenyl ester		甲酸乙烯酯			C₃H₄O₂		-		0.127		-	-		0.118		0.140
191	Pentanoic acid, 2,4-dimethyl-, methyl ester		2,4-二甲基-丁酸甲酯			C₈H₁₆O₂		-		-		-	0.527		-		-
192	2-ethyl-3-hydroxyhexyl 2-methylpropanoate		/			C₁₂H₂₄O₃		0.024		0.035		0.020	0.024		0.020		0.021
193	ethyl 2-methylbutanoate		2-甲基丁酸乙酯			C₇H₁₄O₂		-		-		-	-		-		0.884
194	E-2-Hexenyl benzoate		顺2-己烯-1-醇苯甲酸酯			C₁₃H₁₆O₂		0.036		-		-	-		-		-
195	(Z,Z,Z)-6,9,12-Octadecatrienoic acid, phenylmethyl ester		/			C₂₅H₃₆O₂		-		-		-	0.043		0.273		-
196	Arachic acid benzyl ester		/			C₂₇H₄₆O₂		-		0.016		-	-		-		-
197	5,8,11,14-Eicosatetraenoic acid, phenylmethyl ester, (all-Z)-		/			C₂₇H₃₈O₂		-		-		-	0.004		-		-
198	Propanoic acid, 2-methyl-, 3-hydroxy-2,2,4-trimethylpentyl ester		/			C₁₂H₂₄O₃		0.036		0.033		-	0.024		-		-
199	ACETIC ACID 2-METHYLPENTYL ESTER		乙酸-2-甲基戊酯			C₈H₁₆O₂		0.127		-		-	0.064		-		-
200	methyl acetate		乙酸甲酯			C₃H₆O₂		0.141		-		-	0.199		0.243		0.142
201	BUTYL OCTYL PHTHALATE		邻苯二甲酸正丁异辛酯			C₂₀H₃₀O₄		-		0.006		0.004	0.004		0.009		0.004
202	methyl 2-methylbutanoate		2-甲基丁酸甲酯			C₆H₁₂O₂		0.276		0.269		0.217	0.184		0.322		0.250
203	sec-Butyl nitrite		硝酸-1甲基-丙酯			C₄H₉NO₂		0.016		0.006		0.007	0.013		0.010		0.016
204	D,L-ISOBORNYL ACETATE		异冰片基乙酯			C₁₂H₂₀O₂		-		0.011		0.016	0.015		-		0.016
205	2-Propenoic acid,isotridecyl ester		/			C₁₇H₂₂O₂		0.004		-		-	-		-		-
206	α-methyl-benzenemethanol acetate		乙酸苏合香酯			C₁₀H₁₂O₂		-		0.032		0.040	0.052		0.098		-
207	ethyl 2-methylpropanoate		异丁酸乙酯			C₆H₁₂O₂		0.078		-		-	-		-		0.060
208	3-Methylanisole		间甲基苯甲醚			C₈H₁₀O		-		-		-	0.052		-		-
209	ISOSAFROLE		异黄樟素			C₁₀H₁₀O₂		-		-		-	0.013		-		-

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