新疆农业科学 ›› 2021, Vol. 58 ›› Issue (10): 1791-1801.DOI: 10.6048/j.issn.1001-4330.2021.10.004
• 作物遗传育种·种质资源·分子遗传学·耕作栽培·生理生化·农产品分析检测 • 上一篇 下一篇
吴忠红1(), 裴龙英2(), 张健1, 姜璐熙2, 孔建军1, 杜鹃3, 吴斌1
收稿日期:
2020-09-11
出版日期:
2021-10-20
发布日期:
2021-10-26
通信作者:
裴龙英
作者简介:
吴忠红(1979-),女,新疆乌鲁木齐人,副研究员,博士,研究方向为农产品贮藏加工,(E-mail) wuzhonghong111@163.com
基金资助:
Zhonghong WU1(), Longying PEI2(), Jian ZHANG1, Luxi JIANG2, Jianjun KONG1, Juan DU3, Bin WU1
Received:
2020-09-11
Online:
2021-10-20
Published:
2021-10-26
Correspondence author:
Longying PEI
Supported by:
摘要:
【目的】分析5个品种甜瓜籽油的挥发性风味成分与脂肪酸之间的关系。【方法】采用气相色谱-质谱联用仪测定不同品种甜瓜籽油的挥发性风味成分和脂肪酸,采用R语言分析PCA和变量投影重要性。【结果】5个品种甜瓜籽油中共鉴定出65种挥发性化合物,新蜜1号样品检测到的挥发性物质种类最多为37种,皇后品种的油脂中有30种,香瓜和86-1样品中有29种,绿宝石样品检测到最少,为26种,分析发现5个样品之间的挥发性物质有显著性差异。5个品种甜瓜籽油在挥发性物质成分共分成4大类,皇后与绿宝石较相近归为一类。5种甜瓜籽油中富含不饱和脂肪酸,平均为75.34%,其中亚油酸最高,平均含量达56.81%。【结论】二十四酸、十八碳烯酸、花生酸、棕榈酸、亚麻酸、蓖麻油酸与某些香气物质有较强相关性。
中图分类号:
吴忠红, 裴龙英, 张健, 姜璐熙, 孔建军, 杜鹃, 吴斌. 亚临界提取甜瓜籽油风味与脂肪酸关系分析[J]. 新疆农业科学, 2021, 58(10): 1791-1801.
Zhonghong WU, Longying PEI, Jian ZHANG, Luxi JIANG, Jianjun KONG, Juan DU, Bin WU. Study on the Relationship between Flavor and Fatty Acids of Melon Seed Oil Extracted by Subcritical Method[J]. Xinjiang Agricultural Sciences, 2021, 58(10): 1791-1801.
序号 Serial number | 出峰 时间 Penk time (min) | RI | 化合物名称 Compound name | 甜瓜品种 Melon variety (%) | |||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
香瓜 Xiang gua | 皇后 Queen | 绿宝石 Lübaoshi | 86-1 Eight six-one | 新蜜1号 Xinmi No.1 | |||||||||||
醇类 | |||||||||||||||
1 | 15.65 | 1 102 | 芳樟醇 | nd | nd | nd | nd | 0.55±0.04 | |||||||
2 | 16.09 | 1 118 | 苯乙醇 | 0.6±0.03c | 0.29±0.0b | 0.33±0.01b | 0.83±0.02d | 0.14±0.00a | |||||||
3 | 18.00 | 1 186 | 2-莰醇 | 0.94±0.02c | 0.86±0.04c | 0.8±0.11c | 0.63±0.01b | 0.43±0.01a | |||||||
4 | 18.37 | 1 206 | 2-甲基2-辛烯4-醇 | nd | nd | nd | 0.32±0.01 | nd | |||||||
5 | 18.42 | 1 212 | 4-萜烯醇 | 1.16±0.01d | 1.09±0.01c | 1.08±0.02c | 0.85±0.03b | 0.7±0.01a | |||||||
6 | 18.91 | 1 230 | α-松油醇 | 0.58±0.01b | 0.7±0.0e | 0.53±0.01a | 0.64±0.01d | 0.62±0.02c | |||||||
7 | 19.91 | 1 244 | (1R,5R)-香芹醇 | nd | 0.17±0.00a | 0.16±0.01a | 0.16±0.00a | 0.17±0.00a | |||||||
8 | 23.527 | 1 386 | 3,5-二甲基己醇 | nd | 0.27±0.01 | nd | nd | nd | |||||||
9 | 24.194 | 1 422 | 蒽紫素 | 0.19±0.01 | nd | nd | nd | nd | |||||||
萜烯类 | |||||||||||||||
10 | 8.01 | 846 | 1,3,5,7-环辛四烯 | 0.62±0.01 | nd | nd | nd | nd | |||||||
11 | 9.26 | 916 | α-侧柏烯 | nd | nd | nd | nd | 0.13±0.00 | |||||||
12 | 9.45 | 922 | 左旋-α-蒎烯 | 1.77±0.03 | nd | nd | nd | nd | |||||||
13 | 9.47 | 930 | 右旋-α-蒎烯 | nd | 6.74±0.1c | 11.1±0.8e | 9.26±0.7d | 2.93±0.1b | |||||||
14 | 10.98 | 970 | β-蒎烯 | 8.83±0.14 | nd | nd | nd | nd | |||||||
15 | 11.15 | 976 | 左旋-β-蒎烯 | nd | 10.46±0.31b | 11.21±0.21c | 11.16±0.14c | 16.59±0.16d | |||||||
16 | 11.59 | 988 | 月桂烯 | 7.28±0.15a | 9.27±0.89bc | 9.11±0.35bc | 8.32±0.25ab | 10.43±0.53c | |||||||
17 | 12.24 | 998 | (1S)-(+)-3-蒈烯 | 24.31±1.01b | 26.49±0.61bc | 26.55±1.22bc | 28.03±1.24c | nd | |||||||
18 | 12.33 | 1 010 | 3-蒈烯 | nd | nd | nd | nd | 33.85±1.98 | |||||||
19 | 12.94 | 1 023 | 右旋萜二烯 | 15.46±0.46 | nd | nd | nd | nd | |||||||
20 | 12.96 | 1 030 | 双戊烯 | nd | 16.38±1.14b | 15.92±0.55b | 14.96±1.95b | nd | |||||||
21 | 13.72 | 1 040 | 罗勒烯 | nd | 0.15±0.01c | 0.16±0..00c | 0.03±0.00b | 0.2±0.01d | |||||||
22 | 16.39 | 1 056 | α-水芹烯 | 0.42±0.01b | 0.62±0.01c | 0.66±0.02c | 0.32±0.01a | 0.89±0.07d | |||||||
23 | 16.40 | 1 134 | 芬烯 | nd | nd | nd | nd | 0.17±0.01 | |||||||
24 | 18.32 | 1 193 | 黏蒿三烯 | 0.31±0.01b | 0.42±0.01d | 0.39±0.00c | nd | nd | |||||||
25 | 18.71 | 1 225 | 2,4-二甲基苯乙烯 | nd | nd | nd | nd | 0.28±0.01 | |||||||
26 | 19.80 | 1 240 | (3E,5E)-2,6-二甲基 -1,3,5,7-辛四烯 | 0.17±0.00 | nd | nd | nd | nd | |||||||
27 | 23.945 | 1 394 | 萜品油烯 | nd | nd | 0.23±0.01 | nd | nd | |||||||
28 | 24.44 | 1 473 | 3-乙烯基-1,2-二甲基 -1,4-环己二烯 | 0.16±0.01c | nd | nd | 0.09±0.00b | nd | |||||||
29 | 24.49 | 1 486 | 4-甲基-1,4-庚二烯 | nd | 0.17±0.00 | nd | nd | nd | |||||||
30 | 25.201 | 1 510 | α-蒎烯 | 0.28±0.01a | 0.36±0.01b | 0.31±0.01ab | 0.46±0.01c | 1.15±0.05d | |||||||
31 | 25.744 | 1 533 | β-榄香烯 | nd | nd | nd | nd | 0.51±0.02 | |||||||
32 | 25.948 | 1 552 | 2,5-二甲基-2,4-己二烯 | nd | nd | nd | nd | 0.16±0.01 | |||||||
33 | 26.61 | 1 586 | β-石竹烯 | 3.92±0.35a | 4.51±0.48ab | 4.16±0.72ab | 5.45±0.45b | 14.89±0.35d | |||||||
34 | 27.67 | 1 588 | α-石竹烯 | 0.15±0.03b | 0.2±0.03c | nd | nd | nd | |||||||
35 | 28.68 | 1 592 | β-芹子烯 | 0.04±0.01b | 0.09±0.01c | nd | 0.05±0.00b | 0.17±0.01d | |||||||
序号 Serial number | 出峰 时间 Penk time (min) | RI | 化合物名称 Compound name | 甜瓜品种 Melon variety (%) | |||||||||||
香瓜 Xiang gua | 皇后 Queen | 绿宝石 Lübaoshi | 86-1 Eight six-one | 新蜜1号 Xinmi No.1 | |||||||||||
酮类 | |||||||||||||||
36 | 15.82 | 1 110 | α-侧柏酮 | 1.2±0.06c | 1.23±0.05c | 1.24±0.04c | 0.84±0.04b | 0.38±0.02a | |||||||
37 | 16.93 | 1 164 | 胡薄荷酮 | nd | nd | nd | 0.17±0.01c | 0.06±0.00b | |||||||
45 | 17.23 | 1 178 | 2-茨酮 | 3.26±0.05b | 3.1±0.13b | 3.08±0.06b | 3.25±0.24b | 1.39±0.14a | |||||||
38 | 17.90 | 1 184 | 松香芹酮 | 0.14±0.01b | 0.16±0.02b | 0.15±0.01b | nd | nd | |||||||
39 | 19.62 | 1 234 | 4,6,6-三甲基二环-3- 庚烯-2-酮 | 0.18±0.03ab | 0.25±0.02d | 0.2±0.02bc | 0.18±0.01ab | 0.13±0.02a | |||||||
40 | 20.792 | 1 262 | 右旋香芹酮 | 0.04±0.00a | 0.04±0.01a | 0.06±0.01a | 0.05±0.01a | 0.04±0.01a | |||||||
41 | 21.161 | 1 270 | 胡椒酮 | 0.15±0.03ab | 0.16±0.01ab | 0.16±0.01ab | 0.17±0.01b | 0.13±0.01a | |||||||
42 | 21.76 | 1 322 | 异佛尔酮 | nd | nd | 0.13±0.01 | nd | nd | |||||||
43 | 21.93 | 1 356 | 3,5-二甲基-2-环己烯 -1-酮 | nd | 0.11±0.01c | nd | nd | 0.08±0.01b | |||||||
44 | 26.29 | 1 563 | 3-正-丙基-2-吡唑啉 -5-酮 | nd | nd | nd | nd | 0.2±0.01 | |||||||
醛类 | |||||||||||||||
46 | 10.31 | 950 | (E)-2-庚烯醛 | 0.2±0.01e | 0.19±0.00d | 0.16±0.01c | nd | 0.06±0.01b | |||||||
47 | 10.40 | 964 | 苯甲醛 | nd | nd | nd | 0.64±0.05 | nd | |||||||
48 | 16.73 | 1 143 | 2,4,6-三甲基-3-环己烯 -1-甲醛 | 0.31±0.01b | 0.27±0.02b | 0.27±0.04b | nd | nd | |||||||
49 | 18.69 | 1 220 | 桃金娘烯醛 | 0.27±0.05b | 0.29±0.05b | 0.31±0.08b | 0.27±0.06b | nd | |||||||
50 | 20.631 | 1 254 | 对异丙基苯甲醛 | 0.09±0.01a | 0.16±0.03b | 0.1±0.02a | 0.18±0.01b | 0.09±0.01a | |||||||
51 | 24.23 | 1 430 | 2-乙基己烯醛 | nd | 0.2±0.02b | 0.25±0.04bc | 0.28±0.03c | nd | |||||||
酯类 | |||||||||||||||
52 | 13.97 | 1 048 | γ-己内酯 | nd | nd | nd | 0.14±0.01 | nd | |||||||
53 | 17.78 | 1 182 | 三甲基甲硅烷醇三硅 甲烷氧基水杨酯 | 0.18±0.02b | nd | 0.23±0.03c | nd | nd | |||||||
54 | 23.728 | 1 392 | 双(三甲硅基)草酸酯 | nd | 0.17±0.02 | nd | nd | nd | |||||||
55 | 24.761 | 1 496 | 丙位壬内酯 | nd | 0.19±0.02c | nd | 0.28±0.02d | 0.07±0.01b | |||||||
酚类 | |||||||||||||||
59 | 14.74 | 1 072 | 4-甲基苯酚 | nd | nd | nd | nd | 0.15±0.02 | |||||||
56 | 20.23 | 1 251 | 对异丙基苯酚 | nd | nd | nd | nd | 0.19±0.01 | |||||||
57 | 22.76 | 1 366 | 香芹酚 | nd | nd | nd | nd | 0.12±0.01 | |||||||
58 | 24.583 | 1 490 | 丁香酚 | nd | nd | nd | 0.11±0.03 | nd | |||||||
其他类 | |||||||||||||||
63 | 12.79 | 1 007 | 对异丙基甲苯 | 2.80±0.05c | 0.07±0.00b | nd | nd | nd | |||||||
64 | 12.80 | 1 020 | 邻异丙基甲苯 | nd | 3.81±0.12d | 4.56±0.37e | 3.16±0.26c | 2.06±0.27b | |||||||
65 | 21.385 | 1 276 | 4-乙基邻二甲苯 | 0.06±0.00b | nd | 0.09±0.01c | 0.06±0.00b | 0.06±0.00b | |||||||
60 | 22.16 | 1 364 | 环十二烷 | nd | nd | nd | nd | 0.2±0.02 | |||||||
61 | 23.257 | 1 373 | 叔戊基环己烷 | 0.24±0.01b | nd | nd | 0.37±0.01b | 1.01±0.1c | |||||||
62 | 24.30 | 1 436 | 1-甲基-4-(1-甲基 丁基)环己烷 | nd | nd | nd | nd | 0.71±0.03 |
表1 不同品种甜瓜籽油挥发性物质的GC-MS鉴定
Table 1 GC-MS identification results of volatile substances in melon seed oil of different varieties
序号 Serial number | 出峰 时间 Penk time (min) | RI | 化合物名称 Compound name | 甜瓜品种 Melon variety (%) | |||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
香瓜 Xiang gua | 皇后 Queen | 绿宝石 Lübaoshi | 86-1 Eight six-one | 新蜜1号 Xinmi No.1 | |||||||||||
醇类 | |||||||||||||||
1 | 15.65 | 1 102 | 芳樟醇 | nd | nd | nd | nd | 0.55±0.04 | |||||||
2 | 16.09 | 1 118 | 苯乙醇 | 0.6±0.03c | 0.29±0.0b | 0.33±0.01b | 0.83±0.02d | 0.14±0.00a | |||||||
3 | 18.00 | 1 186 | 2-莰醇 | 0.94±0.02c | 0.86±0.04c | 0.8±0.11c | 0.63±0.01b | 0.43±0.01a | |||||||
4 | 18.37 | 1 206 | 2-甲基2-辛烯4-醇 | nd | nd | nd | 0.32±0.01 | nd | |||||||
5 | 18.42 | 1 212 | 4-萜烯醇 | 1.16±0.01d | 1.09±0.01c | 1.08±0.02c | 0.85±0.03b | 0.7±0.01a | |||||||
6 | 18.91 | 1 230 | α-松油醇 | 0.58±0.01b | 0.7±0.0e | 0.53±0.01a | 0.64±0.01d | 0.62±0.02c | |||||||
7 | 19.91 | 1 244 | (1R,5R)-香芹醇 | nd | 0.17±0.00a | 0.16±0.01a | 0.16±0.00a | 0.17±0.00a | |||||||
8 | 23.527 | 1 386 | 3,5-二甲基己醇 | nd | 0.27±0.01 | nd | nd | nd | |||||||
9 | 24.194 | 1 422 | 蒽紫素 | 0.19±0.01 | nd | nd | nd | nd | |||||||
萜烯类 | |||||||||||||||
10 | 8.01 | 846 | 1,3,5,7-环辛四烯 | 0.62±0.01 | nd | nd | nd | nd | |||||||
11 | 9.26 | 916 | α-侧柏烯 | nd | nd | nd | nd | 0.13±0.00 | |||||||
12 | 9.45 | 922 | 左旋-α-蒎烯 | 1.77±0.03 | nd | nd | nd | nd | |||||||
13 | 9.47 | 930 | 右旋-α-蒎烯 | nd | 6.74±0.1c | 11.1±0.8e | 9.26±0.7d | 2.93±0.1b | |||||||
14 | 10.98 | 970 | β-蒎烯 | 8.83±0.14 | nd | nd | nd | nd | |||||||
15 | 11.15 | 976 | 左旋-β-蒎烯 | nd | 10.46±0.31b | 11.21±0.21c | 11.16±0.14c | 16.59±0.16d | |||||||
16 | 11.59 | 988 | 月桂烯 | 7.28±0.15a | 9.27±0.89bc | 9.11±0.35bc | 8.32±0.25ab | 10.43±0.53c | |||||||
17 | 12.24 | 998 | (1S)-(+)-3-蒈烯 | 24.31±1.01b | 26.49±0.61bc | 26.55±1.22bc | 28.03±1.24c | nd | |||||||
18 | 12.33 | 1 010 | 3-蒈烯 | nd | nd | nd | nd | 33.85±1.98 | |||||||
19 | 12.94 | 1 023 | 右旋萜二烯 | 15.46±0.46 | nd | nd | nd | nd | |||||||
20 | 12.96 | 1 030 | 双戊烯 | nd | 16.38±1.14b | 15.92±0.55b | 14.96±1.95b | nd | |||||||
21 | 13.72 | 1 040 | 罗勒烯 | nd | 0.15±0.01c | 0.16±0..00c | 0.03±0.00b | 0.2±0.01d | |||||||
22 | 16.39 | 1 056 | α-水芹烯 | 0.42±0.01b | 0.62±0.01c | 0.66±0.02c | 0.32±0.01a | 0.89±0.07d | |||||||
23 | 16.40 | 1 134 | 芬烯 | nd | nd | nd | nd | 0.17±0.01 | |||||||
24 | 18.32 | 1 193 | 黏蒿三烯 | 0.31±0.01b | 0.42±0.01d | 0.39±0.00c | nd | nd | |||||||
25 | 18.71 | 1 225 | 2,4-二甲基苯乙烯 | nd | nd | nd | nd | 0.28±0.01 | |||||||
26 | 19.80 | 1 240 | (3E,5E)-2,6-二甲基 -1,3,5,7-辛四烯 | 0.17±0.00 | nd | nd | nd | nd | |||||||
27 | 23.945 | 1 394 | 萜品油烯 | nd | nd | 0.23±0.01 | nd | nd | |||||||
28 | 24.44 | 1 473 | 3-乙烯基-1,2-二甲基 -1,4-环己二烯 | 0.16±0.01c | nd | nd | 0.09±0.00b | nd | |||||||
29 | 24.49 | 1 486 | 4-甲基-1,4-庚二烯 | nd | 0.17±0.00 | nd | nd | nd | |||||||
30 | 25.201 | 1 510 | α-蒎烯 | 0.28±0.01a | 0.36±0.01b | 0.31±0.01ab | 0.46±0.01c | 1.15±0.05d | |||||||
31 | 25.744 | 1 533 | β-榄香烯 | nd | nd | nd | nd | 0.51±0.02 | |||||||
32 | 25.948 | 1 552 | 2,5-二甲基-2,4-己二烯 | nd | nd | nd | nd | 0.16±0.01 | |||||||
33 | 26.61 | 1 586 | β-石竹烯 | 3.92±0.35a | 4.51±0.48ab | 4.16±0.72ab | 5.45±0.45b | 14.89±0.35d | |||||||
34 | 27.67 | 1 588 | α-石竹烯 | 0.15±0.03b | 0.2±0.03c | nd | nd | nd | |||||||
35 | 28.68 | 1 592 | β-芹子烯 | 0.04±0.01b | 0.09±0.01c | nd | 0.05±0.00b | 0.17±0.01d | |||||||
序号 Serial number | 出峰 时间 Penk time (min) | RI | 化合物名称 Compound name | 甜瓜品种 Melon variety (%) | |||||||||||
香瓜 Xiang gua | 皇后 Queen | 绿宝石 Lübaoshi | 86-1 Eight six-one | 新蜜1号 Xinmi No.1 | |||||||||||
酮类 | |||||||||||||||
36 | 15.82 | 1 110 | α-侧柏酮 | 1.2±0.06c | 1.23±0.05c | 1.24±0.04c | 0.84±0.04b | 0.38±0.02a | |||||||
37 | 16.93 | 1 164 | 胡薄荷酮 | nd | nd | nd | 0.17±0.01c | 0.06±0.00b | |||||||
45 | 17.23 | 1 178 | 2-茨酮 | 3.26±0.05b | 3.1±0.13b | 3.08±0.06b | 3.25±0.24b | 1.39±0.14a | |||||||
38 | 17.90 | 1 184 | 松香芹酮 | 0.14±0.01b | 0.16±0.02b | 0.15±0.01b | nd | nd | |||||||
39 | 19.62 | 1 234 | 4,6,6-三甲基二环-3- 庚烯-2-酮 | 0.18±0.03ab | 0.25±0.02d | 0.2±0.02bc | 0.18±0.01ab | 0.13±0.02a | |||||||
40 | 20.792 | 1 262 | 右旋香芹酮 | 0.04±0.00a | 0.04±0.01a | 0.06±0.01a | 0.05±0.01a | 0.04±0.01a | |||||||
41 | 21.161 | 1 270 | 胡椒酮 | 0.15±0.03ab | 0.16±0.01ab | 0.16±0.01ab | 0.17±0.01b | 0.13±0.01a | |||||||
42 | 21.76 | 1 322 | 异佛尔酮 | nd | nd | 0.13±0.01 | nd | nd | |||||||
43 | 21.93 | 1 356 | 3,5-二甲基-2-环己烯 -1-酮 | nd | 0.11±0.01c | nd | nd | 0.08±0.01b | |||||||
44 | 26.29 | 1 563 | 3-正-丙基-2-吡唑啉 -5-酮 | nd | nd | nd | nd | 0.2±0.01 | |||||||
醛类 | |||||||||||||||
46 | 10.31 | 950 | (E)-2-庚烯醛 | 0.2±0.01e | 0.19±0.00d | 0.16±0.01c | nd | 0.06±0.01b | |||||||
47 | 10.40 | 964 | 苯甲醛 | nd | nd | nd | 0.64±0.05 | nd | |||||||
48 | 16.73 | 1 143 | 2,4,6-三甲基-3-环己烯 -1-甲醛 | 0.31±0.01b | 0.27±0.02b | 0.27±0.04b | nd | nd | |||||||
49 | 18.69 | 1 220 | 桃金娘烯醛 | 0.27±0.05b | 0.29±0.05b | 0.31±0.08b | 0.27±0.06b | nd | |||||||
50 | 20.631 | 1 254 | 对异丙基苯甲醛 | 0.09±0.01a | 0.16±0.03b | 0.1±0.02a | 0.18±0.01b | 0.09±0.01a | |||||||
51 | 24.23 | 1 430 | 2-乙基己烯醛 | nd | 0.2±0.02b | 0.25±0.04bc | 0.28±0.03c | nd | |||||||
酯类 | |||||||||||||||
52 | 13.97 | 1 048 | γ-己内酯 | nd | nd | nd | 0.14±0.01 | nd | |||||||
53 | 17.78 | 1 182 | 三甲基甲硅烷醇三硅 甲烷氧基水杨酯 | 0.18±0.02b | nd | 0.23±0.03c | nd | nd | |||||||
54 | 23.728 | 1 392 | 双(三甲硅基)草酸酯 | nd | 0.17±0.02 | nd | nd | nd | |||||||
55 | 24.761 | 1 496 | 丙位壬内酯 | nd | 0.19±0.02c | nd | 0.28±0.02d | 0.07±0.01b | |||||||
酚类 | |||||||||||||||
59 | 14.74 | 1 072 | 4-甲基苯酚 | nd | nd | nd | nd | 0.15±0.02 | |||||||
56 | 20.23 | 1 251 | 对异丙基苯酚 | nd | nd | nd | nd | 0.19±0.01 | |||||||
57 | 22.76 | 1 366 | 香芹酚 | nd | nd | nd | nd | 0.12±0.01 | |||||||
58 | 24.583 | 1 490 | 丁香酚 | nd | nd | nd | 0.11±0.03 | nd | |||||||
其他类 | |||||||||||||||
63 | 12.79 | 1 007 | 对异丙基甲苯 | 2.80±0.05c | 0.07±0.00b | nd | nd | nd | |||||||
64 | 12.80 | 1 020 | 邻异丙基甲苯 | nd | 3.81±0.12d | 4.56±0.37e | 3.16±0.26c | 2.06±0.27b | |||||||
65 | 21.385 | 1 276 | 4-乙基邻二甲苯 | 0.06±0.00b | nd | 0.09±0.01c | 0.06±0.00b | 0.06±0.00b | |||||||
60 | 22.16 | 1 364 | 环十二烷 | nd | nd | nd | nd | 0.2±0.02 | |||||||
61 | 23.257 | 1 373 | 叔戊基环己烷 | 0.24±0.01b | nd | nd | 0.37±0.01b | 1.01±0.1c | |||||||
62 | 24.30 | 1 436 | 1-甲基-4-(1-甲基 丁基)环己烷 | nd | nd | nd | nd | 0.71±0.03 |
挥发物种类 Volatile species | 种类/含量 Type/Content(%) | ||||
---|---|---|---|---|---|
香瓜 Xiang gua | 皇后 Queen | 绿宝石 Lübaoshi | 86-1 Eight six-one | 新蜜1号 Xinmi No.1 | |
醇类 Alcohols | 5 / 3.47±0.02c | 6 / 3.38±0.05c | 5 / 2.9±0.11b | 6 / 3.43±0.04c | 6 / 2.61±0.03a |
萜烯类 Terpenes | 14 / 63.72±1.45a | 13 / 75.86±0.84b | 11 / 79.8±0.95c | 11 / 78.13±0.66bc | 14 / 82.35±2.5cd |
酮类 Ketones | 6 / 4.97±0.06c | 7 / 5.05±0.20c | 7 / 5.02±0.04c | 6 / 4.66±0.22b | 8 / 2.41±0.14a |
醛类 Aldehydes | 4 / 0.87±0.04b | 5 / 1.11±0.12c | 5 / 1.08±0.03c | 4 / 1.37±0.03d | 2 / 0.15±0.01a |
酯类 Esters | 1 / 0.18±0.04b | 2 / 0.36±0.12d | 1 / 0.23±0.04c | 2 / 0.42±0.03e | 1 / 0.07±0.01a |
酚类 Phenols | nd | nd | nd | 1 / 0.11±0.02b | 3 / 0.46±0.04c |
其他类 Other classes | 3 / 3.1±0.04a | 2 / 3.88±0.12b | 2 / 4.65±0.36c | 3 / 3.59±0.27ab | 5 / 4.04±0.44b |
表2 不同品种甜瓜籽油挥发性化合物种类及含量变化
Table 2 Changes of volatile compounds in seed oil of different melon varieties
挥发物种类 Volatile species | 种类/含量 Type/Content(%) | ||||
---|---|---|---|---|---|
香瓜 Xiang gua | 皇后 Queen | 绿宝石 Lübaoshi | 86-1 Eight six-one | 新蜜1号 Xinmi No.1 | |
醇类 Alcohols | 5 / 3.47±0.02c | 6 / 3.38±0.05c | 5 / 2.9±0.11b | 6 / 3.43±0.04c | 6 / 2.61±0.03a |
萜烯类 Terpenes | 14 / 63.72±1.45a | 13 / 75.86±0.84b | 11 / 79.8±0.95c | 11 / 78.13±0.66bc | 14 / 82.35±2.5cd |
酮类 Ketones | 6 / 4.97±0.06c | 7 / 5.05±0.20c | 7 / 5.02±0.04c | 6 / 4.66±0.22b | 8 / 2.41±0.14a |
醛类 Aldehydes | 4 / 0.87±0.04b | 5 / 1.11±0.12c | 5 / 1.08±0.03c | 4 / 1.37±0.03d | 2 / 0.15±0.01a |
酯类 Esters | 1 / 0.18±0.04b | 2 / 0.36±0.12d | 1 / 0.23±0.04c | 2 / 0.42±0.03e | 1 / 0.07±0.01a |
酚类 Phenols | nd | nd | nd | 1 / 0.11±0.02b | 3 / 0.46±0.04c |
其他类 Other classes | 3 / 3.1±0.04a | 2 / 3.88±0.12b | 2 / 4.65±0.36c | 3 / 3.59±0.27ab | 5 / 4.04±0.44b |
序号 Serial number | 脂肪酸 Fatty acid | 种类/含量 Type/Content(%) | ||||
---|---|---|---|---|---|---|
香瓜 Xiang gua | 皇后 Queen | 绿宝石 Lübaoshi | 86-1 Eight six-one | 新蜜1号 Xinmi No.1 | ||
饱和脂肪酸 | 3 / 20.42±0.10a | 4 / 20.99±0.32a | 3 / 24.16±1.39b | 3 / 29.21±1.2c | 4 / 20.1±0.01a | |
1 | 肉豆蔻酸 | nd | 0.09±0.00 | nd | nd | nd |
11 | 花生酸 | 0.53±0.05d | 0.2±0.02b | nd | nd | 0.36±0.04c |
3 | 棕榈酸 | 12.75±0.18a | 14.38±0.66b | 13.29±0.12a | 16.27±0.26c | 13.31±0.07a |
13 | 二十四酸 | nd | nd | nd | nd | 0.14±0.00 |
12 | 18-甲基十九烷酸 | nd | nd | 0.75±0.02b | 1.00±0.08c | nd |
6 | 硬脂酸 | 7.14±0.17a | 6.32±0.67a | 10.12±1.25b | 11.94±1.66c | 6.29±0.12a |
不饱和脂肪酸 | 4 / 79.38±1.19c | 3 / 78.56±0.39c | 5 / 72.87±3.11b | 3 / 66.84±4.01a | 4 / 79.06±1.53c | |
7 | 亚麻酸 | nd | nd | 0.18±0.01 | nd | nd |
8 | 十八碳烯酸 | nd | nd | nd | nd | 1.36±0.09 |
9 | 蓖麻油酸 | nd | nd | 0.22±0.05 | nd | nd |
10 | 顺式-13-二十碳烯酸 | 0.14±0.01b | nd | 0.26±0.04c | 0.31±0.04d | nd |
2 | 十六烯酸 | 0.18±0.01b | 0.16±0.01b | nd | nd | 0.16±0.01b |
4 | 亚油酸 | 54.24±1.01b | 61.7±1.5c | 59.73±1.62c | 49.25±2.24a | 59.14±0.85c |
5 | 油酸 | 24.82±1.68c | 16.7±1.10b | 12.48±1.45a | 17.28±1.73b | 18.4±0.78b |
表3 不同品种甜瓜籽油脂肪酸鉴定
Table 3 Identification results of fatty acids in melon seed oil of different varieties
序号 Serial number | 脂肪酸 Fatty acid | 种类/含量 Type/Content(%) | ||||
---|---|---|---|---|---|---|
香瓜 Xiang gua | 皇后 Queen | 绿宝石 Lübaoshi | 86-1 Eight six-one | 新蜜1号 Xinmi No.1 | ||
饱和脂肪酸 | 3 / 20.42±0.10a | 4 / 20.99±0.32a | 3 / 24.16±1.39b | 3 / 29.21±1.2c | 4 / 20.1±0.01a | |
1 | 肉豆蔻酸 | nd | 0.09±0.00 | nd | nd | nd |
11 | 花生酸 | 0.53±0.05d | 0.2±0.02b | nd | nd | 0.36±0.04c |
3 | 棕榈酸 | 12.75±0.18a | 14.38±0.66b | 13.29±0.12a | 16.27±0.26c | 13.31±0.07a |
13 | 二十四酸 | nd | nd | nd | nd | 0.14±0.00 |
12 | 18-甲基十九烷酸 | nd | nd | 0.75±0.02b | 1.00±0.08c | nd |
6 | 硬脂酸 | 7.14±0.17a | 6.32±0.67a | 10.12±1.25b | 11.94±1.66c | 6.29±0.12a |
不饱和脂肪酸 | 4 / 79.38±1.19c | 3 / 78.56±0.39c | 5 / 72.87±3.11b | 3 / 66.84±4.01a | 4 / 79.06±1.53c | |
7 | 亚麻酸 | nd | nd | 0.18±0.01 | nd | nd |
8 | 十八碳烯酸 | nd | nd | nd | nd | 1.36±0.09 |
9 | 蓖麻油酸 | nd | nd | 0.22±0.05 | nd | nd |
10 | 顺式-13-二十碳烯酸 | 0.14±0.01b | nd | 0.26±0.04c | 0.31±0.04d | nd |
2 | 十六烯酸 | 0.18±0.01b | 0.16±0.01b | nd | nd | 0.16±0.01b |
4 | 亚油酸 | 54.24±1.01b | 61.7±1.5c | 59.73±1.62c | 49.25±2.24a | 59.14±0.85c |
5 | 油酸 | 24.82±1.68c | 16.7±1.10b | 12.48±1.45a | 17.28±1.73b | 18.4±0.78b |
图3 不同品种的甜瓜籽油香气物质与脂肪酸的相关性 注:comp1~comp65代表不同香气物质与表1编号一致;fa1~fa13代表不同脂肪酸与表3编号一致2.5 不同品种的甜瓜籽油香气物质与脂肪酸的变量投影
Fig.3 Correlation analysis between aroma compounds and fatty acids in melon seed oil of five varieties Note: comp1-comp65 represents different aroma substances, which are consistent with the numbers in Table 1; fa1-fa13 represent different fatty acids, which are consistent with the numbers in table 3
图4 不同品种的甜瓜籽油香气物质与脂肪酸的变量投影 注:fa1~fa13代表不同脂肪酸与表3编号一致3 讨论
Fig.4 Analysis on the importance of variable projection of aroma compounds and fatty acids in melon seed oil of five varieties Note: fa1-fa13 represent different fatty acids, which are consistent with the numbers in table 3
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