库尔勒香梨枝干生物炭对重金属Cu2+的吸附性能研究

Study on the adsorption performance of heavy metal Cu2+ by biochar from Korla Fragrant Pear branches

  • 摘要:
    目的 为探索农业废弃物再生资源循环附加值提升途径。
    方法 以库尔勒香梨枝干为原料制作的生物炭(BAA)作为吸附剂进行了BAA对Cu2+的吸附影响试验,利用扫描电镜SEM、FTIR傅里叶红外和XRD射线衍射等方法探索BAA吸附Cu2+的特性,探究了不同吸附时间、Cu2+溶液初始浓度、生物炭吸附剂投加量、Cu2+溶液初始pH值对Cu2+的吸附影响,用拟一级、二级动力学模型、2种吸附等温线判断吸附类型。
    结果 BAA对Cu2+的吸附动力学更符合准二级动力学模型,等温吸附曲线符合Langmuir模型,温度50 ℃、pH值为2~4条件下,香梨枝干生物炭吸附铜离子在240 min之内可达到吸附平衡,香梨枝干生物炭最佳投加量分别为1.6 g/L,铜离子初始浓度为50 mg/L,最大吸附量分别为32.11 mg/g,吸附过程符合二级动力学方程,说明其吸附过程主要是近似单分子层的化学吸附。

     

    Abstract:
    Objective To explore the approach of recycling of agricultural waste renewable resources.
    Methods The copper ions by biochar from Korla pear branches was used as adsorbent, and the characteristics of copper adsorption by biochar were investigated by scanning electron microscopy, FTIR infrared and XRD, and the adsorption effects of adsorption time, initial concentration of solution, adsorption temperature, adsorbent dosage, initial pH of solution and other factors on the adsorption of copper ions of biochar in pear branches were explored. Afterwards, the adsorption kinetics and isothermal characteristics of adsorption were discussed.
    Results Under the conditions of temperature of 50 °C and pH of 3~6, the adsorption equilibrium of copper ions could be reached within 240 min, and the optimal dosage of biochar was 1.6 g/L, the initial concentration of copper ions was 100 mg/L and the maximum adsorption capacity were 32.11 mg/g, respectively, the adsorption process conforms to the second-order kinetic equation, and the isothermal adsorption curve conformed to the Langmuir model, indicating that the adsorption process is mainly similar to the chemical adsorption of the monolayer.

     

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